Journal of Fundamentals of Renewable Energy and Applications
Open Access
ISSN: 2090-4541
+44 1300 500008
ISSN: 2090-4541
+44 1300 500008
Aqeel Al-Ani and Vladimir Zholobenko
Keele University, UK
Posters & Accepted Abstracts: J Fundam Renewable Energy App
Recent progress in the synthesis of novel structures and preparation of zeolite nano-crystals and hierarchical materials stimulated developments in many areas, including nanostructured catalysts, advanced coatings, flexible films and membranes for medicine, sensor applications, etc. Biodiesel is a renewable fuel that can be manufactured from oil crops, animal fats, or recycled oil. It contains oxygen and is sulphur-free making it a cleaner burning fuel than petrol and diesel with reduced emissions of SOx, CO, unburnt hydrocarbons and particulate matter. Commercial biodiesel is produced from renewable resources including canola, sunflower or soya bean oil, which are composed of C14ΓΆΒ?Β?C20 fatty acid triglycerides, via esterification and transesterification processes. Esterification occurs when carboxylic acids react with alcohol in the presence of a catalytic amount of mineral acids yielding esters. Transesterification can be performed using homogeneous basic catalysts including sodium and potassium hydroxides, carbonates or alkoxides. However, the removal of the base after the reaction is a major problem since aqueous quenching results in the formation of stable emulsions and saponification, making separation of the methyl ester difficult. The use of a heterogeneous basic or acidic catalyst offers several advantages including the elimination of the quenching step, and associated contaminated water waste, to isolate the products, and the opportunity to operate in a continuous process. In this project, we aim to investigate the potential of composite materials combining base-modified high silica zeolites, such as beta (BEA) and ZSM-5(MFI), and titanosilicates, e.g. ETS-10, targeting the catalytic production of the second generation bio-diesel. Utilising their organophilic-hydrophobic surface properties and changing the acid-base behaviour of these multifunctional catalysts may provide a new approach towards managing the transesterification and esterification reaction in one-pot. Our work is focused on the preparation and modification of nanostructured catalysts, making use of the structure promoters. Both catalytic testing and characterisation of these materials using a wide range of techniques (FTIR, XRD, NMR, GC-MS, adsorption studies, etc.) would inform the preparation conditions in order to improve the overall catalytic performance. Furthermore, reaction testing using microwave heating as a highly efficient energy consumption technology is compared with the traditional reaction systems utilising conventional heating.
Email: a.a.t.al-ani@keele.ac.uk