Journal of Physical Chemistry & Biophysics
Open Access
ISSN: 2161-0398
+44 1478 350008
ISSN: 2161-0398
+44 1478 350008
K C Hall1, D Webber1, M Yildirim1, L Hacquebard1, S March1, R Mathew1, A Gamouras1, X Liu2, M Dobrowolska2 and J K Furdyna2
1Dalhousie University, Canada 2University of Notre Dame, USA
Scientific Tracks Abstracts: J Phys Chem Biophys
Low-temperature-grown GaAs is currently being applied in a wide range of ultrafast optoelectronic devices, including fast photodetectors and photoconductive components for both CW and time-domain THz photonics. The attractive properties of this material for such applications, including a large dark resistivity and short photocarrier lifetime, stem from the introduction of excess As in the form of AsGa point defects during growth at low temperatures.A comprehensive understanding of the ultrafast response of LT-GaAs is essential to optimize device performance as well as to further applications of related low-temperaturegrown semiconductors including III-Mn-V spintronic materials and LT-InGaAs. We have applied femtosecond four-wave mixing to study the coherent carrier response of LT-GaAs. These experiments reveal clear signatures associated with the free-carrierinterband transitions, the Urbach band tail, and the fundamental exciton. The latter two features are inaccessible using linear spectroscopy due to strong band-edge broadening tied to optical transitions associated with the As impurity band, a contribution we show to be suppressed in the four-wave mixing response due to the enhanced sensitivity to the optical joint density of states relative to linear spectroscopy and the sensitivity of the signal to many-body effects. The spectral structure of the Urbach band tail revealed in our experiments provides a direct measure of the effective band gap in LT-GaAs, and will provide input into theoretical models of the electronic structure in the presence of As-related disorder.
Kimberley C Hall completed her PhD at the University of Toronto in 2002, followed by Post-doctoral studies at the University of Iowa. Since 2004, she has been a Faculty Member in the Department of Physics and Atmospheric Science at Dalhousie University and holds a Canada Research Chair in Ultrafast Science. At Dalhousie University, she directs a research group focused on ultrafast spectroscopy and quantum control in semiconductor materials.
Email: Kimberley.Hall@dal.ca